Can SQL Server be configured to backup to a network share through a separate NIC?

We're in the process having our SQL Server instances backup to a network share, but our network admins want to try and divert the bandwidth from the backups through a different network segment. I was curious if it were possible to configure SQL Server to run all backups through a secondary NIC?

Most of our servers are virtualized (so presenting the NIC isn't a problem) and we're running on SQL Server 2008 R2, 2012, & 2014 throughout our infrastructure.